- atom in a carbene. For this
reason stable borylenes are more
uncommon than
stable carbenes. Some
borylenes such as
boron monofluoride (BF) and
boron monohydride...
- hydride,
typically named -ane or -ine.
borenium cations, R2B+ (protonated
borylenes a.k.a. boranylidenes)
carbenium cations, R3C+ (protonated carbenes) have...
- the
field of
transition metal-boron
multiple bonding (transition
metal borylenes), the
synthesis of the
first stable compounds containing boron-boron and...
-
fluorine atoms,
compared with
boron trifluoride. It can also be
called a
borylene, as it
contains boron with two
unshared electrons. BF is isoelectronic...
- and are
prepared through either a
rearrangement or a
borylene pathway as
shown in
Scheme 1:
Borylene addition is a
widely utilized method for the synthesis...
- Borane(1),
boron monohydride,
hydridoboron or
borylene is the
molecule with the
formula BH. It
exists as a gas but
rapidly degrades when condensed. By...
-
centered molecules (e.g., low
valent main
group metal calcium,
dicoordinate borylene,
boron radical, carbene, etc.).
Dinitrogen fixation is
essential for human...
- CAAC-MCl2 complex.
CAACS have also been
shown to
stabilize nucleophilic borylenes and
their corresponding radical cations.
Group 14 is
dominated by organic...
-
product is
isoelectronic to an N-heterocyclic carbene.
Related ligands are
borylenes (M–B(R)–M).
Alkylideneboranes (RB=CRR) with a boron–carbon
double bond...
-
molecule of
dinitrogen is
bound by two
transient Lewis-base-stabilized
borylene species. The
resulting dianion was
subsequently oxidized to a
neutral compound...
