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Organometallic compounds with metal-boron
bonds (M–BR2) are
boryl complexes,
corresponding to the
notional boryl anion R2B−.
Related ligands are
borylenes (M–B(R)–M)...
- An N-heterocyclic
carbene boryl anion is an
isoelectronic structure of an N-heterocyclic
carbene (NHC),
where the
carbene carbon is
replaced with a boron...
- CH3(CH2)6CH3 + [pinB]2 →
pinBH + CH3(CH2)7Bpin
These reactions proceed via
boryl complexes. Bis(pinacolato)diboron can also be used as
reducing agent for...
- In chemistry, a
transition metal boryl complex is a
molecular species with a
formally anionic boron center coordinated to a
transition metal. They have...
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extraordinarily rare.
Strong bases do not
deprotonate a
borohydride R2BH to the
boryl anion R2B−,
instead forming the octet-complete
adduct R2HB-base. In the...
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undergoes two-electron
oxidation to
yield the metal-
boryl complex. Such
complexes are
essentially metal-
boryl complexes, in
which the 9-borafluorene ligand...
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oxidation to give the hydroboration-oxidation reaction. In this reaction, the
boryl group in the
generated organoborane is
substituted with a
hydroxyl group...
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Catecholborane oxidatively adds to low
valent metal complexes,
affording boryl complexes. C6H4O2BH + Pt(PR3)2 → (C6H4O2B)Pt(PR3)2H
Process for producing...
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protodeborylation of
vinyl substituent,
recovering N,N-Dimethyl-2-[(pentafluorophenyl)
boryl]aniline
Release of the cis-alkene With
internal alkynes, a
competitive reaction...
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Warren R. Roper,
George R. Whittell, and L.
James Wright. "Transition metal−
boryl compounds: synthesis, reactivity, and structure."
Chemical reviews 98, no...
