-
Hybrids of
boranes and hydrocarbons, the carboranes, are also a well
developed class of compounds. The
development of the
chemistry of
boranes led to innovations...
- Phosphine-
boranes, with the
formula R3−nHnPBH3, are
adducts of
organophosphines and
borane.
Borane adducts with
amines are more
widely used.
Borane makes...
- and carbon; typically, they are
organic derivatives of
borane (BH3), as in the
trialkyl boranes.
Organoboranes and -borates
enable many
chemical transformations...
-
secondary boranes are less common. Tert-butylamine
borane (tBuNH2→BH3) Phosphine-
borane (R3P→BH3)
Borane dimethylsulfide ((CH3)2S→BH3)
Borane–tetrahydrofuran...
-
significant rate
difference in
producing di- and tri-alkyl
boranes is
useful in the
synthesis of
bulky boranes that can
enhance regioselectivity. In
terms of regiochemistry...
-
Borane carbonyl is the
inorganic compound with the
formula H3BCO. This
colorless gas is the
adduct of
borane and
carbon monoxide. It is
usually prepared...
- BCl3 BF BFO BF3 BI3 B2F4 B2Cl4
Acids B(NO3)3 B(OH)3 BPO4 B2(OH)4 BH3O
Boranes BH3 B2H4 B2H6 BH3NH3 B4H10 B5H9 B5H11 B6H10 B6H12 B10H14 B18H22
Boron oxides...
- conjuncto-
boranes,
where the sub-units are
joined by a B-B bond, can be made by
ultra violet irradiation of nido-
boranes. Some B-B
coupled conjuncto-
boranes can...
- Like the
volatile boranes, the
alkyl boranes ignite spontaneously in air. In the 1950s,
several studies examined the use of
boranes as energy-increasing...
-
compounds described by the
polyhedral skeletal electron pair theory, such as
boranes and carboranes.
These molecules derive their stability from
having a completely...
