-
Biradicaloids or
diradicaloids are
molecules with two
radical electrons that have
significant interaction with each other. The two
unpaired electrons...
- in TMM are identical.
Other examples of non-Kekulé
molecules are the
biradicaloid quinodimethanes, that have a six-membered ring with
methylene substituents...
- also
demonstrated that
cyclic alkyl(amino)
carbene (CAAC)-stabilized
biradicaloid DBA can
react with dioxygen, sulfur, and
selenium to
afford the respective...
-
rings of any size. More recently, Clar's rule was
further extended to
biradicaloids in
their singlet state. When
writing a Clar structure, the following...
- 16-Dicyano(2.2)metacyclophane-1,9-diene and
Evidence Supporting the
Proposed Biradicaloid Mechanism". The
Journal of
Organic Chemistry. 73 (2): 451–6. doi:10.1021/jo7019459...
-
categorised as mono- and bi/di-radicals (also
referred to as
bisradicals and
biradicaloids) for
species containing one or two
radical phosphorus centres respectively...
- Miyoshi, Hirokazu; Tobe, Yo****o (2014-04-17). "Indenofluorene congeners:
Biradicaloids and beyond". Pure and
Applied Chemistry. 86 (4): 517–528. doi:10.1515/pac-2014-5043...
- Herbst-Irmer, Regine; Stalke,
Dietmar (2013-01-10). "A
Stable Singlet Biradicaloid Siladicarbene: (L:)2Si".
Angewandte Chemie International Edition. 52...
-
magnetic circular dichroism,
chemistry and
theory of
biradicals and
biradicaloids,
electronic and
vibrational spectroscopy with
polarized light, silicon...
