- 1,1'-
Binaphthyl is an
organic compound with the
formula (C10H7)2. It is one of the
dimers of
naphthalene (or literally:
dimers of naphthyl). A colorless...
- Štěpán; Smrčina,
Martin (2003). "Non-Symmetrically
Substituted 1,1'-
Binaphthyls in
Enantioselective Catalysis".
Chemical Reviews. 103 (8): 3213–3246...
-
chiral atropisomers, as in
various ortho-substituted biphenyls, and in
binaphthyls such as BINAP.
Axial chirality differs from
central chirality (point...
- be
isolated by seed-directed
crystallization of racemates. Thus, 1,1'-
Binaphthyl crystallizes from the melt as
individual enantiomers. In one application...
- and the low
rates of
racemization of 2,2'-disubstituted
biphenyl and
binaphthyl derivatives.
Because steric effects have
profound impact on properties...
-
substoichiometric (catalytic). Many
important chiral ligands are
constructed from the
binaphthyl scaffold and
ultimately derived from
BINOL as a
starting material, BINAP...
- P. J. (1999). "(R)-(+)- and (S)-(−)-2,2'-Bis(Diphenylphosphino)-1,1'-
Binaphthyl (BINAP)".
Organic Syntheses. 76: 6. doi:10.15227/orgsyn.076.0006. Dell'Amico...
- trans-2-(1-pheyl-1-methylethyl)cyclohexanol have been explored. 1,1’-
Binaphthyl-2,2’-diol, or BINOL, has been used as
chiral auxiliary for the asymmetric...
- "Design and
Preparation of 3,3'-Disubstituted 2,2'-Bis(oxazolyl)-1,1'-
binaphthyls (boxax): New
Chiral Bis(oxazoline)
Ligands for
Catalytic Asymmetric Wacker-Type...
- been made by Lin and
coworkers using 2,2′-bis(diphenylphosphino)-1,1′-
binaphthyl (BINAP) and 1,1′-bi-2,2′-naphthol (BINOL) as
chiral ligands.
These ligands...
