- 0inorganic%20compounds.pdf [dead link] Cepanec,
Ivica (2004).
Synthesis of
Biaryls. Elsevier. p. 104. ISBN 0-08-044412-1.
Retrieved 2008-06-18. v t e...
- can be
achieved through the use of a
chiral leaving group on one of the
biaryls or
under oxidative conditions that
utilize chiral amines to set the axial...
- IUPAC, the term
biaryl refers to an ****embly of two
aromatic rings joined by a
single bond,
starting with the simplest, biphenyl.
Biaryls constitute an...
-
Biphenyl (also
known as diphenyl, phenylbenzene, 1,1′-biphenyl,
lemonene or BP) is an
organic compound that
forms colorless crystals.
Particularly in older...
-
produce phenyl alkenes. This
method was
generalized to a
route producing biaryls by
coupling phenylboronic acid with aryl halides. C-C bond
forming processes...
-
significantly improve the
reaction of aryl
halides with
phenols to give
biaryl ethers. This
reaction is
known as
Ullmann condensation. In 1906, I. Goldberg...
- upward, and in
combinations of
linkages that
include tethering (such as in
biaryls),
fusing (edge-to-edge, such as in
anthracene and steroids),
links via...
- free
rotation either by
steric hindrance of the groups, as in
substituted biaryl compounds such as BINAP, or by
torsional stiffness of the bonds, as in the...
- (link) Gooßen,
Lukas J.; Deng, Guojun; Levy,
Laura M. (2006). "Synthesis of
Biaryls via
Catalytic Decarboxylative Coupling". Science. 313 (5787): 662–664....
-
transition metal catalysis. 3. A
highly selective synthesis of
unsymmetrical biaryls and
diarylmethanes by the nickel- or palladium-catalyzed
reaction of aryl-...