-
definition of
atropisomers taking into
account the temperature-dependence ****ociated with the
interconversion of conformers,
specifying that
atropisomers interconvert...
- from the
axial bond or
deviate 30
degrees from the
reference plane.
Atropisomers are
stereoisomers resulting from
hindered rotation about single bonds...
-
interconversion of 1000
seconds or longer), the
species are
termed atropisomers (see:
atropisomerism). The ring-flip of
substituted cyclohexanes constitutes a...
- sp2-hybridized
carbon atoms.
Usually atropisomers are chiral, and as such they are a form of
axial chirality.
Atropisomerism can be
described as conformational...
-
rotation about the aryl–aryl bond is
restricted so it
results in
chiral atropisomers, as in
various ortho-substituted biphenyls, and in
binaphthyls such as...
- naphthyl). A
colorless solid, it has
attracted some
attention because the
atropisomers can be
isolated due to
hindered rotation between the two
naphthyl subunits...
-
Conformers which arise from
single bond rotations, if not
isolatable as
atropisomers, do not
count as
distinct molecular configurations as the
spatial connectivity...
- off-white
powder and is not hygroscopic. It is a 1:1
racemic mixture of
atropisomers. Lesinurad/allopurinol, a fixed-dose
combination drug "Prescription medicines:...
-
compound forms a
variety of
coordination polymers. It also
exhibits atropisomerism. It can form an
internal anhydride featuring a seven-membered ring fused...
-
dehydrogenase enzymes. It is a
yellow pigment. The
structure exhibits atropisomerism, with the two
enantiomers having different biochemical properties. Among...
