Definition of Atropisomerism. Meaning of Atropisomerism. Synonyms of Atropisomerism

- subunits contribute. Commonly, atropisomerism is studied by dynamic nuclear magnetic resonance spectroscopy, since atropisomerism is a form of fluxionality...
- interconversion of 1000 seconds or longer), the species are termed atropisomers (see: atropisomerism). The ring-flip of substituted cyclohexanes constitutes a...
- sp2-hybridized carbon atoms. Usually atropisomers are chiral, and as such they are a form of axial chirality. Atropisomerism can be described as conformational...
- from the axial bond or deviate 30 degrees from the reference plane. Atropisomers are stereoisomers resulting from hindered rotation about single bonds...
- stereogenic atom, but has axial chirality due to restricted rotation (atropisomerism). The barrier to racemization is high due to steric hindrance, which...
- dehydrogenase enzymes. It is a yellow pigment. The structure exhibits atropisomerism, with the two enantiomers having different biochemical properties. Among...
- rotation about the aryl–aryl bond is restricted so it results in chiral atropisomers, as in various ortho-substituted biphenyls, and in binaphthyls such as...
- university in 1978, with the thesis titled "Asymmetric oxidation of phenols. Atropisomerism and optical activity". Following a short period at S**** in the Netherlands...
- particularly where conformation has a role to play: asymmetric synthesis, atropisomerism, organolithium chemistry, remote stereochemical effects and dynamic...
- compound forms a variety of coordination polymers. It also exhibits atropisomerism. It can form an internal anhydride featuring a seven-membered ring fused...