-
Atropisomers are
stereoisomers arising because of
hindered rotation about a
single bond,
where energy differences due to
steric strain or
other contributors...
-
interconversion of 1000
seconds or longer), the
species are
termed atropisomers (see:
atropisomerism). The ring-flip of
substituted cyclohexanes constitutes a...
- from the
axial bond or
deviate 30
degrees from the
reference plane.
Atropisomers are
stereoisomers resulting from
hindered rotation about single bonds...
- sp2-hybridized
carbon atoms.
Usually atropisomers are chiral, and as such they are a form of
axial chirality.
Atropisomerism can be
described as conformational...
-
rotation about the aryl–aryl bond is
restricted so it
results in
chiral atropisomers, as in
various ortho-substituted biphenyls, and in
binaphthyls such as...
-
parallel kinetic resolution.
Chiral switch Crystal system Enantiopure drug
Atropisomer Chirotechnology Chirality (physics)
Diastereomer Dynamic stereochemistry...
- the
spherical law of cosines, but can also be
found by
other means.
Atropisomer "Angle
Between Two Planes". TutorVista.com.
Archived from the original...
-
sterically hindered. For this reason, some
substituted biphenyls show
atropisomerism; that is, the
individual C2-symmetric-isomers are
optically stable....
-
stereogenic atom, but has
axial chirality due to
restricted rotation (
atropisomerism). The
barrier to
racemization is high due to
steric hindrance, which...
- naphthyl). A
colorless solid, it has
attracted some
attention because the
atropisomers can be
isolated due to
hindered rotation between the two
naphthyl subunits...
