Definition of Antiperiplanarity. Meaning of Antiperiplanarity. Synonyms of Antiperiplanarity

Here you will find one or more explanations in English for the word Antiperiplanarity. Also in the bottom left of the page several parts of wikipedia pages related to the word Antiperiplanarity and, of course, Antiperiplanarity synonyms and on the right images related to the word Antiperiplanarity.

Definition of Antiperiplanarity

No result for Antiperiplanarity. Showing similar results...

Meaning of Antiperiplanarity from wikipedia

- conformational lock. Adjacent substituents on a cyclohexane ring can achieve antiperiplanarity only when they occupy trans diaxial positions (that is, both are in...
- In organic chemistry, anti-periplanar, or antiperiplanar, describes the A−B−C−D bond angle in a molecule. In this conformer, the dihedral angle of the...
- leaving groups (often a hydrogen and a halogen) need to be antiperiplanar. An antiperiplanar transition state has staggered conformation with lower energy...
- the necessity of the oxygen-oxygen bond in the peroxide group to be antiperiplanar to the group that migrates. This orientation facilitates optimum overlap...
- = 180 ∘ {\displaystyle \omega =180^{\circ }} for the trans isomer (antiperiplanar conformation). Amide groups can isomerize about the C'–N bond between...
- (ac); ±150° to 180° antiperiplanar (ap). The synperiplanar conformation is also known as the syn- or cis-conformation; antiperiplanar as anti or trans;...
- hyperconjugation is that the bonds donating and accepting electron density are antiperiplanar to each other, to allow for maximum orbital overlap. The Cieplak effect...
- of the interacting lobes) must be well-matched for interaction; an antiperiplanar orientation is especially favorable. Some authors require stereoelectronic...
- conformation energy diagram of butane as a function of dihedral angle. A: antiperiplanar, anti or trans. B: synclinal or gauche. C: anticlinal or eclipsed. D: synperiplanar...
- Robinson annulation reaction scheme. The trans compound is favored due to antiperiplanar effects of the final aldol condensation in kinetically controlled reactions...