-
triacetoxyborohydride (STAB, NaBH(OAc)3) is a
common reducing agent for
reductive aminations. STAB
selectively reduces the
imine intermediate formed through dehydration...
- 1021/ja00092a058 Guram, A.S.; Buchwald, S.L. (1994), "Palladium-Catalyzed
Aromatic Aminations with in situ
Generated Aminostannanes", J. Am. Chem. Soc., 116 (17): 7901–7902...
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Amination is the
process by
which an
amine group is
introduced into an
organic molecule. This type of
reaction is
important because organonitrogen compounds...
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Other electron-deficient, sp3
amination reagents react by
similar mechanisms to give
substitution products. In
aminations involving oxaziridines, nucleophilic...
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Transamination is a
chemical reaction that
transfers an
amino group to a
ketoacid to form new
amino acids.This
pathway is
responsible for the deamination...
-
Deamination is the
removal of an
amino group from a molecule.
Enzymes that
catalyse this
reaction are
called deaminases. In the
human body, deamination...
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aldehydes but not most ketones. It is
especially suitable for
reductive aminations of
aldehydes and ketones. However,
unlike sodium cyanoborohydride, the...
-
Retrieved 24
September 2019.
Baxter EW,
Reitz AB (April 2004). "Reductive
aminations of
carbonyl compounds with
borohydride and
borane reducing agents". Organic...
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aldehydes or
ketones to amines. The
reaction is an
example of
reductive amination. The reaction,
named after Rudolf Leuckart, uses
either ammonium formate...
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prepared starting from
phenylacetone by
either the
Leuckart or
reductive amination methods. In the
Leuckart reaction, one
equivalent of
phenylacetone is...