-
sides of a
coordination complex. In
contrast to
polydentate ligands,
ambidentate ligands can
attach to the
central atom in
either one of two (or more)...
- much-less-stable
fulminate anion, CNO− or [C−≡N+−O−]. The
cyanate ion is an
ambidentate ligand,
forming complexes with a
metal ion in
which either the nitrogen...
- In chemistry,
linkage isomerism or
ambidentate isomerism is a form of
isomerism in
which certain coordination compounds have the same
composition but...
-
thiocyanate can act as a
nucleophile at
either sulfur or nitrogen—it is an
ambidentate ligand. [SCN]− can also
bridge two (M−SCN−M) or even
three metals (>SCN−...
-
isolated as a salt. When used as a ligand, the
phosphaethynolate anion is
ambidentate in
nature meaning it
forms complexes by
coordinating via
either the phosphorus...
- and
crystallographic studies of
cationic complexes of Me Hg(II) with
ambidentate and
polydentate ligands containing pyridyl and N-substituted imidazolyl...
-
means that
methylation with MeI
tends to
occur at the "softer" end of an
ambidentate nucleophile. For example,
reaction with
thiocyanate ion
favours attack...
-
sulfanilic acid and naphthyl-1-amine in the
presence of acid.
Nitrite is an
ambidentate ligand and can form a wide
variety of
coordination complexes by binding...
-
occurs with
ligands with more than one
possible donor atom,
known as
ambidentate ligands. For example,
nitrite can
coordinate through O or N. One pair...
-
Thiocyanate can bind
metals at
either sulfur or nitrogen — it is an
ambidentate ligand.
Other factors, e.g.
kinetics and solubility,
sometimes influence...
