-
Grignard reagents or
Grignard compounds are
chemical compounds with the
general formula R−Mg−X,
where X is a
halogen and R is an
organic group, normally...
- The
organic halide reactant can be alkenyl, aryl, allyl, or propargyl.
Alkylzinc coupling with
alkyl halides such as
bromides and
chlorides have also been...
- been
reached though several studies have shed
light on this process.
Alkylzinc species form higher-order
zincate species prior to
transmetalation whereas...
- and triflates.
CPhos mediated reactions performed with
secondary (sp3)
alkylzinc halides often give
excellent yields, with low
conversion to the frequently...
- (1860–1934)
extended this
reaction to a
general synthesis of
alcohols using alkylzinc iodides. This
synthesis was the best way to make
alcohols until the advent...
-
compound to be
generated in situ from the
appropriate alkyne with an
alkylzinc reagent or zinc triflate, Zn(OTf)2. The
first example of
catalytic asymmetric...
-
synthesize palladacycle precatalysts for
Negishi coupling of
secondary alkylzinc reagents with aryl halides.
AlPhos allows for the mild Pd-catalyzed fluorination...
-
electrophilic methods is large.
Alkyl Grignard reagents,
alkylithium compounds,
alkylzinc compounds, and
alkylcuprates have been
aminated with
electrophilic reagents...
-
promotes reaction of
alkyl halides, aryl
halides or
alkyl sulfonates with
alkylzinc halides, and the
important advantage of
PEPPSI over
alternative catalysts...
- Cross-Coupling of 2° RAEs (2016) Alkyl-Alkyl Cross-Coupling
Enabled by RAEs and
Alkylzinc Reagents (2016) Ni-catalyzed cross-coupling of RAEs with
Boronic Acids...
