-
reagents have
overtaken Grignard reagents in
common usage.
Although simple alkyllithium species are
often represented as
monomer RLi, they
exist as aggregates...
- iron
complex called ferroin.
Alkyllithium reagents form
deeply colored derivatives with phenanthroline. The
alkyllithium content of
solutions can be determined...
- Lochmann-Schlosser base)
describes various superbasic mixtures of an
alkyllithium compound and a pot****ium alkoxide. The
reagent is
named after Manfred...
-
organic chemistry, and
consists of a 1,2-rearrangement of an
ether with an
alkyllithium compound. The
reaction is
named for
Nobel Prize winning chemist Georg...
- Srzic, D.; Klasinc, Leo (1986). "M****
spectrometric investigations of
alkyllithium compounds in the gas phase". The
Journal of
Physical Chemistry. 90 (10):...
- Lithium–halogen
exchange is
frequently used to
prepare vinyl-, aryl- and
primary alkyllithium reagents.
Vinyl halides usually undergo lithium–halogen
exchange with...
- 1021/ja01863a054. Lochmann, L; Trekoval, J (1987). "Lithium-pot****ium
exchange in
alkyllithium/pot****ium t-pentoxide systems".
Journal of
Organometallic Chemistry....
-
Chemical class Structural formula Prefix Suffix Example Alkyllithium RLi (tri/di)alkyl- -lithium
methyllithium Alkylmagnesium halide RMgX (X=Cl, Br, I)[note...
- the
alkyllithium by
treatment with copper(I)
iodide (CuI) in a
transmetalation reaction: 2 RLi + CuI → Li+[R–Cu–R]– + LiI If the use of
alkyllithium reagents...
-
scheme 1. An
aromatic ring
system with a DMG
group 1
interacts with an
alkyllithium such as n-butyllithium in its
specific aggregation state (hence (R-Li)n)...