- In
organic chemistry, a
carbyne is a
general term for any
compound whose structure consists of an
electrically neutral carbon atom
connected by a single...
- one
alkoxide ligand. This
reaction course remains viable for the new
alkylidynes with
silanolate ligands. Specifically,
compound 29
could be isolated...
-
metal back-donate to the LUMO of the carbyne. They are also
called metal alkylidynes—the
carbon is a
carbyne ligand. Such
compounds are
useful in organic...
- "Multiple
metal carbon Bonds. 35. A
General Route to tri-tert-Butoxytungsten
Alkylidyne complexes.
Scission of
Acetylenes by
Ditungsten Hexa-tert-butoxide". Organometallics...
- give RC≡W(O-t-Bu)3,
tetrahedral alkylidyne complexes. In
these complexes,
tungsten is
electrophilic and the
alkylidyne carbon is nucleophilic. W2(O−t−Bu)6...
-
developing new
catalyst architectures, and
elucidating how
alkylidenes and
alkylidynes are
formed naturally from olefins. In 2005,
Schrock received the Nobel...
- Stefan; Moore,
Jeffrey S. (2004). "Highly
Active Trialkoxymolybdenum(VI)
Alkylidyne Catalysts Synthesized by a
Reductive Recycle Strategy".
Journal of the...
-
Transition Metal Complexes Containing Oxo, Nitrido, Imido, Alkylidene, or
Alkylidyne Ligands" W. A.
Nugent and J. M. Mayer; Wiley-Interscience, New York, 1988...
- Mo-based
catalysts are
active for
olefin metathesis. Trisamidomolybdenum(VI)
alkylidyne complexes catalyze alkyne metathesis. In the
Kauffmann olefination, molybdenum(III)...
-
metal carbonyls. In the 1960s his
group discovered a
metal alkylidene and
alkylidyne complexes,
since referred to as
Fischer carbenes and Fischer-carbynes...
