Definition of Alkylidyne. Meaning of Alkylidyne. Synonyms of Alkylidyne

- In organic chemistry, a carbyne is a general term for any compound whose structure consists of an electrically neutral carbon atom connected by a single...
- studies show that the conversion proceeds via the intermediacy of metal alkylidyne complexes. The reaction is related to olefin metathesis. Metal-catalyzed...
- "Multiple metal carbon Bonds. 35. A General Route to tri-tert-Butoxytungsten Alkylidyne complexes. Scission of Acetylenes by Ditungsten Hexa-tert-butoxide". Organometallics...
- Stefan; Moore, Jeffrey S. (2004). "Highly Active Trialkoxymolybdenum(VI) Alkylidyne Catalysts Synthesized by a Reductive Recycle Strategy". Journal of the...
- metal back-donate to the LUMO of the carbyne. They are also called metal alkylidynes—the carbon is a carbyne ligand. Such compounds are useful in organic...
- give RC≡W(O-t-Bu)3, tetrahedral alkylidyne complexes. In these complexes, tungsten is electrophilic and the alkylidyne carbon is nucleophilic. W2(O−t−Bu)6...
- abstraction reaction, which creates alkylidene complexes from alkyls and alkylidyne complexes from alkylidenes. At MIT Schrock was the first to elucidate...
- Mo-based catalysts are active for olefin metathesis. Trisamidomolybdenum(VI) alkylidyne complexes catalyze alkyne metathesis. In the Kauffmann olefination, molybdenum(III)...
- Loss of Molecular Hydrogen from Tungsten(IV) Alkyl Complexes To Give Alkylidyne Complexes". Journal of the American Chemical Society. 116 (26): 12103–12104...
- metal carbonyls. In the 1960s his group discovered a metal alkylidene and alkylidyne complexes, since referred to as Fischer carbenes and Fischer-carbynes...