-
common reagent is bis(pinacolato)diboron.
Carbon monoxide reacts with
alkylboranes to form an
unstable borane carbonyl. Then an
alkyl substituent migrates...
- N-oxide with
catalytic tetrapropylammonium perruthenate converts the
alkylborane into a carbonyl, thus a
ketone or
aldehyde product depending on what...
-
directly or
indirectly from diborane.
Diborane reacts with
alkenes to give
alkylboranes, a
process known as hydroboration: B2H6 + 2 CH2=CHR → 2 BH2(CH2CH2R)...
-
Triethylborane (TEB), also
called triethylboron, is an
organoborane (a
compound with a B–C bond). It is a
colorless pyrophoric liquid. Its
chemical formula...
- electron-deficient
alkenes such as
acrylic acid derivatives, and for the
oxidation of
alkylboranes to alcohols, the
second step of hydroboration-oxidation. It is also the...
- 2005, 127, 12513-12515. (doi:10.1021/ja052185l) Barton-McCombie @ organic-chemistry.org
Chemical &
Engineering News
article on
alkylborane reaction...
- doi:10.1016/S0022-328X(98)01055-9. Matos, K.; Soderquist, J. A. (1998). "
Alkylboranes in the Suzuki−Miyaura Coupling:
Stereochemical and
Mechanistic Studies"...
-
hydroboration is
widely practiced because the
alkylboranes are
susceptible to many reactions.
Treatment of
alkylboranes with base and
hydrogen peroxide gives...
-
Disiamylborane (bis(1,2-dimethylpropyl)borane) is an
organoborane with the
formula [((CH3)2CHCH(CH3))2BH]2 (abbreviation: Sia2BH). It is a
colorless waxy...
- 1,1-Dimethyldiborane is the
organoboron compound with the
formula (CH3)2B(μ-H)2BH2. A pair of
related 1,2-dimethyldiboranes are also known. It is a colorless...
