- An
older terminology of syn and anti was used to
identify especially aldoximes according to
whether the R
group was
closer or
further from the hydroxyl...
- enzymology, an
aliphatic aldoxime dehydratase (EC 4.99.1.5) is an
enzyme that
catalyzes the
chemical reaction an
aliphatic aldoxime ⇌ {\displaystyle \rightleftharpoons...
-
configuration of
double bonds is
nowadays obsolete,
especially in case of
aldoximes and
hydrazones derived from aldehydes. Here, the
compounds were designated...
-
leading to the
formation of both regioisomers. The
rearrangement of
aldoximes occurs with
stereospecificity in the gas
phase and
without stereospecificity...
-
Pralidoxime (2-pyridine
aldoxime methyl chloride) or 2-PAM,
usually as the
chloride or
iodide salts,
belongs to a
family of
compounds called oximes that...
-
electrochemical processes. The
conversion of
aldehydes to
nitriles via
aldoximes is a po****r
laboratory route.
Aldehydes react readily with hydroxylamine...
- to
aldehydes and ketones, and for
converting epoxides into
alkenes and
aldoximes into nitriles. It can also
cyclize 2-aminoalcohols to
aziridines and to...
- "Thionyl chloride-benzotriazole: an
efficient system for
transformation of
aldoximes to nitriles".
Synthetic Communications. 29 (10): 1741–1745. doi:10...
-
allylic alcohols react faster than
saturated alcohols,
while DMP
oxidizes aldoximes and
ketoximes to
their respective aldehydes and ketones,
faster than a...
-
cations are
isoelectronic with
carbonyls and
structurally related to
aldoximes (hydroxylamines), and
aminoxyl (nitroxide) radicals, with
which they can...
