- In
organometallic chemistry,
agostic interaction refers to the
intramolecular interaction of a coordinatively-unsaturated
transition metal with an appropriately...
-
reaction of a Vaska's
complex with
methyl iodide. Some
metal alkyls feature agostic interactions between a C-H bond on the
alkyl group and the metal. Such...
- interactions,
including σ-bonding, π-bonding, metal-to-metal bonding,
agostic interactions, bent bonds, three-center two-electron
bonds and three-center...
- A
particularly common subset of
sigma complexes are
those featuring an
agostic interaction where a C–H σ-bond on one of its
ligands 'leans'
towards and...
- has been seen
forming a
coordination to lead in [2,4,6-(CF3)3C6H2]2Pb.
Agostic interactions have also been
shown to
stabilize plumbylenes. DFT com****tions...
- metal-bonded
hydride and an alkene. Both α- and β-eliminations
proceed via
agostic intermediates.
Elimination reaction,
mainly focused on
organic substrates...
- William; Wills, Corinne; Clegg, William; Harrington, Ross W. (2008). "
Agostic-Type...Pb
Interactions Stabilize a Dialkylplumbylene.
Structure of and...
-
ligands extend to
include dihydrogen and
hydrocarbons that
interact by
agostic interactions. X
ligands are
halides and pseudohalides. X
ligands typically...
- Carbon–Hydrogen–Titanium Interactions:
Synthesis and
Crystal Structures of the
Agostic alkyls [TiCl3(Me2PCH2CH2PMe2)R] (R = Et or Me)". J. Chem. Soc., Dalton...
- β-hydride
elimination than d2 and
higher metal alkyls and may form
isolable agostic complexes, even if an
empty coordination site is available. The β-hydride...
