- (Ag2O),
which produces AgOTf in 98% yield. It is used to
prepare alkyl triflates from
alkyl halides: CF3SO2OAg + RX → CF3SO2OR +
AgX (X =
iodide usually)...
- water: MCl n + n HOTf ⟶ M (
OTf ) n + n HCl MCl n + n
AgOTf ⟶ M (
OTf ) n + n
AgCl ↓ M ( SO 4 ) n + n Ba (
OTf ) 2 ⟶ M (
OTf ) 2 n + n BaSO 4 ↓ {\displaystyle...
- Pictet–Spengler reaction. This
reaction can also be
catalyzed by AuCl3 and
AgOTf. When the Pictet–Spengler
reaction is
performed with an
aldehyde other than...
- can be
activated under a wide
range of conditions, most
notably using NIS/
AgOTf.
Trichloroacetimidates were
first introduced and
explored by
Schmidt in...
- Additionally, a
variety of
activation methods can be emplo****, such as NIS/
AgOTf, NIS/ TfOH, IDCP (Iodine
Dicollidine Perchlorate), iodine, and Ph2SO/ Tf2O...
-
typically activated via
halide abstraction with
silver salts like
AgOTf,
AgBF4, or
AgSbF6 to
generate a
cationic gold(I) species.
Although the coordinatively...
-
silyl ketene acetal of y-butyrolactone in
presence of
silver triflate (
AgOTf) to give the mono
lactone which upon
reduction with LiAlH4
afforded the...
-
catechin nucleophile and
monomeric catechin electrophile catalyzed by
AgOTf or
AgBF4. The
coupled product can be
transformed into
procyanidin C2 by a known...
-
catechin nucleophile and
monomeric catechin electrophile catalyzed by
AgOTf or
AgBF4. The
coupled product can be
transformed into
procyanidin C2 by a known...
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