-
absent from
propionic acid and is
found exclusively in the ethanol. In
acyloxy groups the acyl
group is
bonded to oxygen: R−C(=O)−O−R′
where R−C(=O) is...
-
rearrangement is an
organic reaction whereby an
alkyl sulfoxide rearranges to an α-
acyloxy–thioether (monothioacetal-ester) in the
presence of
acetic anhydride. The...
- vol. 10, p. 577. Furuta, K.; Gao, Q.-z.; Yamamoto, H. (1998). "Chiral (
Acyloxy)borane Complex-catalyzed
Asymmetric Diels-Alder Reaction: (1R)-1,3...
- ISBN 978-3-527-30673-2. Furuta, Kyoji; Gao, Qing-Zhi; Yamamoto,
Hisashi (1995). "Chiral (
Acyloxy)borane Complex-Catalyzed
Asymmetric Diels-Alder Reaction: (1R)-1,3...
- isocyanide, an
aldehyde (or ketone), and a
carboxylic acid to form a α-
acyloxy amide. This
addition reaction is one of the
oldest isocyanide-based multicomponent...
-
halides Amides Imides Amidines −COOCO− −COO− −COX −CONH2 −CONC< −CNHNH2
acyloxy- R-oxycarbonyl- halocarbonyl- carbamoyl- -imido- amidino- -R-oic anhydride...
- this is the Baker–Venkataraman rearrangement, in
which an
aromatic ortho-
acyloxy ketone undergoes an
intramolecular nucleophilic acyl
substitution and subsequent...
- +M
hydroxy and
alkoxy groups -OH, -OR
Moderate acylamido groups -NHCOR
acyloxy groups -OCOR (di)alkylphosphino, alkylthio, and
sulfhydryl groups -PR2...
-
Carabateas P,
Grumbach L (1958). "Strong Analgesics. The
Preparation of Some 4-
Acyloxy-1-aralkyl-4-phenylpiperidines".
Journal of the
American Chemical Society...
-
multicomponent reactions are the P****erini 3-component
reaction to
produce α-
acyloxy carboxamides and the Ugi 4-component reaction,
which yields the α-amino...