-
Acrolein (systematic name: propenal) is the
simplest unsaturated aldehyde. It is a
colorless liquid with a foul and
acrid aroma. The
smell of
burnt fat...
- by
conversion to
glycerol carbonate or to
synthetic precursors, such as
acrolein and epichlorohydrin.
Although usually not
economical anymore, glycerol...
- synthesis. In one such
procedure the
reaction of 3-N-tosylaminophenol I with
acrolein II
affords a
hydroxyl substituted quinoline III
through 4
sequential steps...
-
condensation is
accompanied by decarboxylation. For example, the
reaction of
acrolein and
malonic acid in
pyridine gives trans-2,4-entadienoic acid with one...
- to the wine such as the bitter-tasting "
acrolein taint" that
comes from
degradation of
glycerol into
acrolein which then
reacts with
phenolic compounds...
- water.
Double dehydration is
illustrated by the
conversion of
glycerol to
acrolein: The
formation of the
pyrophosphate bond is an
important dehydration relevant...
- and
detoxifies acrolein.
Intermittent dosing of
cyclophosphamide decreases ****ulative drug dose,
reduces bladder exposure to
acrolein and has
equal efficacy...
-
anticancer agents, in vivo, may be
converted to
urotoxic metabolites, such as
acrolein.
Mesna ****ists to
detoxify these metabolites by
reaction of its sulfhydryl...
-
reactivity is
called vinylogous.
Examples of
unsaturated carbonyls are
acrolein (propenal),
mesityl oxide,
acrylic acid, and
maleic acid.
Unsaturated carbonyls...
-
acrolein. In fact, the term
reuterin is the name
given to the
dynamic system formed by 3-hydroxypropionaldehyde, its hydrate, the dimer, and
acrolein...