-
Dimethyl acetylenedicarboxylate (DMAD) is an
organic compound with the
formula CH3O2CC2CO2CH3. It is a di-ester in
which the
ester groups are conjugated...
-
soluble in
diethyl ether. The
removal of two
protons yields the
acetylenedicarboxylate dianion C4O2−4,
which consists only of
carbon and oxygen, making...
- The
enzyme acetylenedicarboxylate decarboxylase (EC 4.1.1.78)
catalyzes the
chemical reaction acetylenedicarboxylate + H2O ⇌ {\displaystyle \rightleftharpoons...
- (HC2O4−).
Other more
exotic carbon–oxygen
anions exist, such as
acetylenedicarboxylate (O2C–C≡C–CO22−),
mellitate (C12O96−),
squarate (C4O42−), and rhodizonate...
- very mild
reaction of a 2-(dimethylamino)thiazole with
dimethyl acetylenedicarboxylate (DMAD) to a
pyridine was
found to
proceed through a zwitterionic...
-
reaction of bis-furyl
dienes 3 with hexafluoro-2-butyne or
dimethyl acetylenedicarboxylate (DMAD) have been
discovered and
described in 2018. At low temperature...
- Baeyer–Emmerling
indole synthesis In the Diels–Reese
reaction dimethyl acetylenedicarboxylate reacts with 1,2-diphenylhydrazine to an adduct,
which in xylene...
- Diels–Reese
Reaction is a
reaction between hydrazobenzene and
dimethyl acetylenedicarboxylate (or
related esters)
first reported in 1934 by Otto
Diels and Johannes...
-
Stetter conditions for
coupling aromatic aldehydes with
dimethyl acetylenedicarboxylate (DMAD),
whereby the
thiazolium ylide is
hydrolyzed by the aromatization...
-
Scientific MSDS
Related compounds Related compounds But-2-yne
Dimethyl acetylenedicarboxylate Except where otherwise noted, data are
given for
materials in their...
